My wife's info was the only one of my contacts that wouldn't sync with FB. I went into FB and did the click on picture and edit contact info in there. I noticed it didnt have her number listed there so I added it. I went into my droid contacts and it still wasnt syncing so I deleted the contact in the droid contacts and re-added it and it started syncing. So maybe try putting their numbers in the FB contact info and then delete the droid contact that isnt syncing and re-adding it. It was instantly updated with her status and profile pic.